{"id":4784,"date":"2024-12-30T20:50:11","date_gmt":"2024-12-30T20:50:11","guid":{"rendered":"https:\/\/www.richardmudhar.com\/blog\/?p=4784"},"modified":"2025-01-13T11:22:29","modified_gmt":"2025-01-13T11:22:29","slug":"paramagnetism-revisited","status":"publish","type":"post","link":"https:\/\/www.richardmudhar.com\/blog\/2024\/12\/paramagnetism-revisited\/","title":{"rendered":"Paramagnetism revisited"},"content":{"rendered":"<p>Been nearly ten years since I <a href=\"https:\/\/www.richardmudhar.com\/blog\/2015\/08\/measuring-paramagnetism-3-a-portable-instrument\/\">last looked at this<\/a>. Most people&#8217;s interest in paramagnetism seemed to be soil testing with the Phil Callahan Soil Meter (PCSM), mine was investigating megalithic sites. I have <a href=\"https:\/\/www.richardmudhar.com\/blog\/2015\/08\/measuring-paramagnetism-3-a-portable-instrument\/#comment-25521\">Fabrice <\/a>to thank for this and much useful information about the PCSM. I had unsatisfactory results in the field, lacking sensitivity. This was probably due to a bad choice of coil design. Looking at Bartington&#8217;s MS2D surface scanning probe, it&#8217;s clear I should have designed this more like a metal detector search coil.<\/p>\n<figure id=\"attachment_4790\" aria-describedby=\"caption-attachment-4790\" style=\"width: 370px\" class=\"wp-caption aligncenter\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-4790\" src=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/MS2D.jpg?resize=370%2C251&#038;ssl=1\" alt=\"\" width=\"370\" height=\"251\" \/><figcaption id=\"caption-attachment-4790\" class=\"wp-caption-text\">Bartington&#8217;s MS2D surface scanning probe shows how it&#8217;s done<\/figcaption><\/figure>\n<p>Which explains why I shelved this project after dismal results at Gors-Fawr I recall.<\/p>\n<figure id=\"attachment_4792\" aria-describedby=\"caption-attachment-4792\" style=\"width: 840px\" class=\"wp-caption aligncenter\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" class=\"size-large wp-image-4792\" src=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?resize=840%2C630&#038;ssl=1\" alt=\"\" width=\"840\" height=\"630\" srcset=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?resize=1024%2C768&amp;ssl=1 1024w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?resize=550%2C413&amp;ssl=1 550w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?resize=768%2C576&amp;ssl=1 768w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?resize=1536%2C1152&amp;ssl=1 1536w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?resize=1200%2C900&amp;ssl=1 1200w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?w=1920&amp;ssl=1 1920w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr.jpg?w=1680&amp;ssl=1 1680w\" sizes=\"auto, (max-width: 709px) 85vw, (max-width: 909px) 67vw, (max-width: 1362px) 62vw, 840px\" \/><figcaption id=\"caption-attachment-4792\" class=\"wp-caption-text\">Gors Fawr measurement fail. I expected this value to be a lot higher<\/figcaption><\/figure>\n<p>Sadly Philip Callahan passed in November 2017, it seems interest has dropped away without such an eloquent protagonist. For the first time i though I would look at soil, which you can enclose in a solenoid, which takes away a lot of the handwaving. I bought some rock dust from <a href=\"https:\/\/www.ebay.co.uk\/itm\/156344990631\">Allgood Farm on ebay<\/a> and thought I&#8217;d investigate. Before we go on I should emphasise that Allgood don&#8217;t say anything about paramagnetism in their description &#8211;<\/p>\n<blockquote><p>Volcanic rock dust is rich in essential minerals and trace elements like magnesium, iron, and calcium that plants need to grow.<br \/>\nSlow Release: These minerals are released slowly over time, providing a long-term nutrient supply.<\/p><\/blockquote>\n<p>so this is about mineralisation, not paramagnetism. The<a href=\"https:\/\/en.wikipedia.org\/wiki\/List_of_volcanoes_in_the_United_Kingdom\"> last volcanic activity in Britain was 50 million years ago<\/a>, so volcanic rock from the UK won&#8217;t be highly paramagnetic, because much will have eroded over 50mn years \ud83d\ude09<\/p>\n<figure id=\"attachment_4786\" aria-describedby=\"caption-attachment-4786\" style=\"width: 1024px\" class=\"wp-caption aligncenter\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" class=\"wp-image-4786 size-full\" src=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5186-coil.jpg?resize=840%2C630&#038;ssl=1\" alt=\"\" width=\"840\" height=\"630\" srcset=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5186-coil.jpg?w=1024&amp;ssl=1 1024w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5186-coil.jpg?resize=550%2C413&amp;ssl=1 550w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5186-coil.jpg?resize=768%2C576&amp;ssl=1 768w\" sizes=\"auto, (max-width: 709px) 85vw, (max-width: 909px) 67vw, (max-width: 1362px) 62vw, 840px\" \/><figcaption id=\"caption-attachment-4786\" class=\"wp-caption-text\">the sample was tested inside the coil, separated for clarity in the picture<\/figcaption><\/figure>\n<p>I used a discrete component Franklin oscillator. I am also testing a LM358 oscillator, on the same breadboard<\/p>\n<figure id=\"attachment_4787\" aria-describedby=\"caption-attachment-4787\" style=\"width: 1024px\" class=\"wp-caption aligncenter\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-4787\" src=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5184-breadboard.jpg?resize=840%2C630&#038;ssl=1\" alt=\"\" width=\"840\" height=\"630\" srcset=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5184-breadboard.jpg?w=1024&amp;ssl=1 1024w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5184-breadboard.jpg?resize=550%2C413&amp;ssl=1 550w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/DSCN5184-breadboard.jpg?resize=768%2C576&amp;ssl=1 768w\" sizes=\"auto, (max-width: 709px) 85vw, (max-width: 909px) 67vw, (max-width: 1362px) 62vw, 840px\" \/><figcaption id=\"caption-attachment-4787\" class=\"wp-caption-text\">opamp and discrete Franklin oscillators on a solderless breadboard<\/figcaption><\/figure>\n<p>It&#8217;s tasteless as hell to make these oscillators on a breadboard, but the discrete component oscillator had a tendency to squegging at these low frequencies so it helped debug that. I have this on DL4YHF&#8217;s Spectrum Lab<\/p>\n<figure id=\"attachment_4788\" aria-describedby=\"caption-attachment-4788\" style=\"width: 908px\" class=\"wp-caption aligncenter\"><img data-recalc-dims=\"1\" loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-4788\" src=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/discrete-osc.png?resize=840%2C672&#038;ssl=1\" alt=\"\" width=\"840\" height=\"672\" srcset=\"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/discrete-osc.png?w=908&amp;ssl=1 908w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/discrete-osc.png?resize=550%2C440&amp;ssl=1 550w, https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/discrete-osc.png?resize=768%2C614&amp;ssl=1 768w\" sizes=\"auto, (max-width: 709px) 85vw, (max-width: 909px) 67vw, (max-width: 1362px) 62vw, 840px\" \/><figcaption id=\"caption-attachment-4788\" class=\"wp-caption-text\">DL4YHF&#8217;s Spectrum Lab trace, 30Hz span<\/figcaption><\/figure>\n<p>and you can see there&#8217;s some scintillation, whether this can be improved by building this on Veroboard remains to be seen. Using Spectrum Lab I measured the frequency f2 at 5.4886 kHz and f1 with sample at 5.4861 kHz.<\/p>\n<p>Using \u03c7 = (f1\u00b2-f2\u00b2)\/(f1\u00b2 \u00d7 4 \u03c0) from <a href=\"https:\/\/www.richardmudhar.com\/blog\/2015\/08\/measuring-paramagnetism-3-a-portable-instrument\/\">last time<\/a><sup id=\"fnref-4784-1\"><a href=\"#fn-4784-1\" class=\"jetpack-footnote\" title=\"Read footnote.\">1<\/a><\/sup> I infer the susceptibility is<\/p>\n<p>(5488.6\u00b2 &#8211; 5486.1\u00b2)\/(5488.6\u00b2 \u00d7 4 \u03c0) = 7.25E-05 = 72 \u00b5CGS. Probably +\/- 5\u00b5CGS given the scintillation in frequency. Definitely paramagnetic, probably not stupendously so. I need to find some powdered materials to calibrate this with. And test the Franklin discrete component oscillator and the LM358 version for stability when soldered, rather than bodged on a breadboard \ud83d\ude09<\/p>\n<p>My coil was ~1.2mH and resonated at ~5.5 kHz with a 1 \u00b5F mylar capacitor and the stray coupling\u00a0 capacitors of the Franklin oscillator. To be continued<\/p>\n<div class=\"footnotes\">\n<hr \/>\n<ol>\n<li id=\"fn-4784-1\">\nNote the \u03c7<sub>m<\/sub> terminology <a href=\"https:\/\/www.richardmudhar.com\/blog\/2015\/08\/measuring-paramagnetism-3-a-portable-instrument\/\">then<\/a> is wrong, it should be \u03c7<sub>v<\/sub>, the dimensionless volume susceptibility&#160;<a href=\"#fnref-4784-1\" title=\"Return to main content.\">&#8617;<\/a>\n<\/li>\n<\/ol>\n<\/div>\n","protected":false},"excerpt":{"rendered":"<p>Been nearly ten years since I last looked at this. Most people&#8217;s interest in paramagnetism seemed to be soil testing with the Phil Callahan Soil Meter (PCSM), mine was investigating megalithic sites. I have Fabrice to thank for this and much useful information about the PCSM. I had unsatisfactory results in the field, lacking sensitivity. &hellip; <a href=\"https:\/\/www.richardmudhar.com\/blog\/2024\/12\/paramagnetism-revisited\/\" class=\"more-link\">Continue reading<span class=\"screen-reader-text\"> &#8220;Paramagnetism revisited&#8221;<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":4791,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_jetpack_newsletter_access":"","_jetpack_dont_email_post_to_subs":false,"_jetpack_newsletter_tier_id":0,"_jetpack_memberships_contains_paywalled_content":false,"_jetpack_memberships_contains_paid_content":false,"footnotes":"","jetpack_publicize_message":"","jetpack_publicize_feature_enabled":true,"jetpack_social_post_already_shared":true,"jetpack_social_options":{"image_generator_settings":{"template":"highway","default_image_id":0,"font":"","enabled":false},"version":2},"jetpack_post_was_ever_published":false},"categories":[57,275,400],"tags":[309],"class_list":["post-4784","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-electronics","category-greenmantle","category-megalithic","tag-paramagnetism"],"jetpack_publicize_connections":[],"jetpack_featured_media_url":"https:\/\/i0.wp.com\/www.richardmudhar.com\/blog\/wp-content\/uploads\/2025\/01\/gors-fawr-circle.jpg?fit=1920%2C1440&ssl=1","jetpack_sharing_enabled":true,"jetpack_shortlink":"https:\/\/wp.me\/p5aOO7-1fa","jetpack_likes_enabled":true,"_links":{"self":[{"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/posts\/4784","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/comments?post=4784"}],"version-history":[{"count":6,"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/posts\/4784\/revisions"}],"predecessor-version":[{"id":4796,"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/posts\/4784\/revisions\/4796"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/media\/4791"}],"wp:attachment":[{"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/media?parent=4784"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/categories?post=4784"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.richardmudhar.com\/blog\/wp-json\/wp\/v2\/tags?post=4784"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}